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TRANSFORMING         TRANSFORMING         TRANSFORMING
         SUSTAINABILITY REPORT  FY 2023                                                                                                                                     COMMUNITIES           THE PLANET         THE WORKPLACE














             Pilot on red mud utilization raises hopes for carbon-light road construction                        Sustainable sodium sulphate management helps in cost reduction and waste valorization










             Utilizing the waste that we produce,       construction material and structural filler,             Hindustan Zinc Limited (HZL) is the country’s             internally generated Na SO  salts now opened up
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             which varies from low to high levels       was explored. The study has been                         largest zinc producer and operates several large          a whole new vista of opportunity as they could be
             of toxicity, in a manner that is           completed and further evaluation is                      smelters. The zinc production process consists            used as a replacement for the commercially
             productive and with neutral impact         awaited.                                                 of various stages and different techniques are            procured ones. The substitution would not only
             on the environment, is an ongoing                                                                   used as per the output desired. Roasting and              help to cut down on operational costs, it would
             priority for us. We regularly              If pilot trials prove successful, the                    leaching are two constituent processes of zinc            significantly further the waste-to-wealth objective
             collaborate with institutions and          potential for utilization of red mud in road             production, with the removal of iron being an             that underpins every aspect of our manufacturing
             organizations that are working on          construction could reach 1.5 MMT per                     essential part of the production cycle. The               operations. Another crucial advantage was the
             allied objectives. Bayer process,          year. This would not only address the                    jarosite process is the most widely used route for        substantial reduction in hazardous waste storage
             which is used for refining bauxite to      environmental issues associated with                     removing iron elements from zinc, and it is               and maintenance costs. The prospect of
             produce alumina, generates                 red mud accumulation but also provide a                  deployed in our smelters, with jarosite emerging          substituting the commercial procured Na SO
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             approximately 3 million metric             sustainable alternative for road                         as the waste byproduct. Our 92000                         crystals with the internally generated ones carried
             tonnes (MMT) of red mud annually,          construction materials. Achieving the                    tonnes-smelter at Debari, near Udaipur in                 a potential for 50% replacement, which meant a
             posing a significant environmental         nation’s growth ambitions in a                           Rajasthan, is a hydrometallurgical zinc smelter           sharp increase in the internal production of these
             hazard in terms of soil and water          carbon-neutral way is essential if India is              and produces High Grade (HG) zinc. In FY                  salts. This would parallelly reduce the volume of
             toxicity. Additionally, at our sites       to meet its Net Zero commitments and                     2022-23, this plant faced a problem as it                 hazardous waste that we are liable to manage,
             there is pre-existing accumulation of      through our ‘Transforming Together’                      witnessed a cost escalation in the zinc sulfide           handle and store as per Hazardous Waste
             around 20 MMT of red mud, which            focus we are collaborating in making this                detector (ZSD) process due to the rising prices           Management Rules, 2016. Clearly there were
             further exacerbates the                    possible.                                                of commercial sodium sulphate (Na SO ) which              several high-impact gains that would originate
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             environmental risk.                                                                                 was used in the Jarosite precipitation stage. The         from this waste valorization initiative.
                                                                                                                 ZSD plant uses nearly 12 -13 MT/day of Na SO .
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             Meanwhile for construction of roads,                                                                Clearly, a cost-effective alternative had to be           The following steps were involved before a
             materials like soil and aggregate                                                                   found else profitability would be significantly           full-fledged transition to in-house Na SO
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             materials are traditionally used. Due                                                               affected.                                                 crystals-based Jarosite precipitation could be
             to the high demand for such                                                                                                                                   done.
             materials from the construction                                                                     Though the challenge pertained to operating               •  First, a study was conducted to assess the
             sector, soil and its aggregates are                                                                 costs, the Plant Operations team decided to take             quality of the internally produced Na SO
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             now severely depleted, and there is a                                                               a comprehensive approach that would address                  crystals and their suitability for use in the
             need for finding viable alternatives.                                                               other priorities too. The Debari smelter has a               Jarosite precipitation process.
             To address these different                                                                          3000 KLD Zero Liquid Discharge plant for
             challenges, Vedanta was recently                                                                    treatment of effluents. The ZLD plant helps to            •  Next, experimental trials were carried out to
             involved in a laboratory-scale study                                                                meet our zero-waste objective. Further, the                  verify the efficacy of Jarosite precipitation with
             conducted by the CSIR-CRRI                                                                          sludge generated from the treatment goes                     these crystals.
             (Central Road Research Institute)                                                                   through a crystallization process, and Na SO              •  Plant trials were then initiated to validate the
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             under which the potential application                                                               crystals are generated as a byproduct. These                 findings on a larger scale.
             of red mud as an alternative




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